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Indicators and the pH Scale

IGCSE 0620 · CBSE Class 10 · Acids, bases and salts
All labs
Distilled water · 25 cm³ No indicator added
50 25
Click the dropper to add 3 drops
pH meter7.00
Indicator says-
[H⁺]1×10⁻⁷ mol/dm³
NatureNeutral
Add the indicatorPick a solution, then click the dropper to add three drops of indicator.
Universal indicator · pH 0-14Full range
Strongly acidicNeutral · 7Strongly alkaline

Universal indicator is a mixture of dyes, so it changes colour gradually across the whole range. A single indicator only flips once, over a narrow band - compare them in the chart below.

Bench console
Indicator
Solutions on the bench
Indicator comparison chart Colour at each pH · white outline = your solution

The pH at which a single indicator changes is its transition range. Outside that range the colour tells you nothing more - phenolphthalein looks identical at pH 1 and pH 7, which is exactly why universal indicator exists.

Syllabus notes
Reactions of acids and alkalis Both syllabuses · with the test for each product

Every reaction below is examinable in IGCSE 0620 and CBSE Class 10. Each one is shown with the observation and the gas test that identifies the product.

1 · Acid + Alkali → Salt + Water

HCl + NaOH → NaCl + H₂O
Ionic: H⁺(aq) + OH⁻(aq) → H₂O(l)

Neutralisation. The H⁺ from the acid and the OH⁻ from the alkali combine to make water - this is why the pH moves towards 7. The reaction is exothermic.

Universal indicator runs green at the neutral point. In a titration you would use phenolphthalein or methyl orange instead, because they give one sharp change.

2 · Acid + Metal → Salt + Hydrogen

Zn + 2HCl → ZnCl₂ + H₂
Mg + H₂SO₄ → MgSO₄ + H₂

Only metals above hydrogen in the reactivity series react. Copper does not.

Test: a lighted splint gives a squeaky pop - hydrogen.

3 · Acid + Metal Carbonate → Salt + Water + Carbon dioxide

Na₂CO₃ + 2HCl → 2NaCl + H₂O + CO₂
CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂

Effervescence - brisk fizzing as CO₂ is released.

Test: the gas turns lime water milky. Ca(OH)₂ + CO₂ → CaCO₃ + H₂O

4 · Acid + Metal Hydrogencarbonate → Salt + Water + Carbon dioxide

NaHCO₃ + HCl → NaCl + H₂O + CO₂

The reaction behind baking soda fizzing in vinegar, and behind an antacid tablet.

Test: lime water turns milky, as above.

5 · Acid + Metal Oxide → Salt + Water

CuO + H₂SO₄ → CuSO₄ + H₂O

A metal oxide is a base. Copper(II) oxide is a base but not an alkali, because it does not dissolve in water - an IGCSE definition point.

Black CuO disappears and a blue copper(II) sulfate solution forms.

6 · Alkali + Ammonium salt → Salt + Water + Ammonia

NH₄Cl + NaOH → NaCl + H₂O + NH₃

Warming is needed. This is the standard test for an ammonium ion.

Test: the gas turns damp red litmus blue - ammonia is the only common alkaline gas.

7 · Dissociation in water - where the ions come from

HCl(aq) → H⁺(aq) + Cl⁻(aq)
CH₃COOH(aq) ⇌ CH₃COO⁻(aq) + H⁺(aq)
NaOH(aq) → Na⁺(aq) + OH⁻(aq)

The single arrow shows a strong acid - it dissociates completely. The reversible arrow shows a weak acid - only a small fraction of molecules release H⁺ at any moment.

Acids show acidic behaviour only in water - H⁺ ions cannot form without it. Dry HCl gas does not turn dry litmus red.

8 · Diluting an acid - the safety rule

Add acid to water · never water to acid

Dilution is strongly exothermic. Adding water to concentrated acid makes the mixture spit and can crack the container.

Diluting lowers the concentration of H⁺ ions per unit volume, so the pH rises towards 7.

Exam practice

What this experiment shows

pH is a measure of how many hydrogen ions are in a solution. The scale runs from 0 to 14 and it is logarithmic, so a solution of pH 3 has ten times as many hydrogen ions as one of pH 4. Universal indicator is a mixture of dyes that gives a different colour at each part of the range - useful for a rough value, but a pH meter is what you use when a number matters.

pH 7 neutral · below 7 acidic · above 7 alkaline

What you need

  • Universal indicator solution or paper
  • A colour chart
  • Solutions of known pH
  • A white tile
  • A pH meter for comparison

How it is done

  1. Put a few drops of the solution on a white tile.
  2. Add one drop of universal indicator, or dip a strip of the paper.
  3. Match the colour against the chart within about 30 seconds.
  4. Record the pH to the nearest whole number.
  5. Check a few against a pH meter to see how rough the estimate is.

What you should see

  • Red at pH 1-2, orange 3-4, yellow 5-6, green 7, blue 8-11, purple 12-14.
  • Strong acids sit at the bottom of the scale, weak acids nearer the middle.
  • Each step of one pH unit is a tenfold change in hydrogen ion concentration.
  • The indicator only gives a whole number - it cannot give 4.3.

Where marks are lost

  • Saying pH 6 is "twice as acidic" as pH 7. It is ten times.
  • Confusing strength with concentration. A concentrated weak acid can have a higher pH than a dilute strong one.
  • Using universal indicator for a titration. It changes over too wide a range - use a single indicator instead.
  • Reading the colour after the paper has dried out.

Questions students ask

What does pH actually measure?
The concentration of hydrogen ions. pH is the negative logarithm of that concentration, which is why each unit is a factor of ten.
Why is universal indicator no good for titrations?
It changes colour gradually over the whole range, so there is no sharp end point. A single indicator that flips over a narrow range is needed.
Is pH 7 always neutral?
At room temperature, yes. The neutral point shifts slightly with temperature because the ionisation of water itself changes.

Try these next

Written for Cambridge IGCSE Chemistry 0620 and CBSE Class 9-12 by Ajay Shekhawat, founder of MrChemCoach. Run the simulator above, then check yourself against the questions.